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Kinetic Monte Carlo simulations of plasma-surface reactions on heterogeneous surfaces

Daniil Marinov

《化学科学与工程前沿(英文)》 2019年 第13卷 第4期   页码 815-822 doi: 10.1007/s11705-019-1837-9

摘要: Reactions of atoms and molecules on chamber walls in contact with low temperature plasmas are important in various technological applications. Plasma-surface interactions are complex and relatively poorly understood. Experiments performed over the last decade by several groups prove that interactions of reactive species with relevant plasma-facing materials are characterized by distributions of adsorption energy and reactivity. In this paper, we develop a kinetic Monte Carlo (KMC) model that can effectively handle chemical kinetics on such heterogenous surfaces. Using this model, we analyse published adsorption-desorption kinetics of chlorine molecules and recombination of oxygen atoms on rotating substrates as a test case for the KMC model.

关键词: plasma-surface interaction     kinetic Monte Carlo     plasma nano technology    

Plasma-enabled healing of graphene nano-platelets layer

Xiuqi Fang, Carles Corbella, Denis B. Zolotukhin, Michael Keidar

《化学科学与工程前沿(英文)》 2019年 第13卷 第2期   页码 350-359 doi: 10.1007/s11705-018-1787-7

摘要: Graphene platelet networks (GPNs) were deposited onto silicon substrates by means of anodic arc discharge ignited between two graphite electrodes. Substrate temperature and pressure of helium atmosphere were optimized for the production of the carbon nanomaterials. The samples were modified or destroyed with different methods to mimic typical environments responsible of severe surface degradation. The emulated conditions were performed by four surface treatments, namely thermal oxidation, substrate overheating, exposition to glow discharge, and metal coating due to arc plasma. In the next step, the samples were regenerated on the same substrates with identical deposition technique. Damaging and re-growth of GPN samples were systematically characterized by scanning electron microscopy and Raman spectroscopy. The full regeneration of the structural and morphological properties of the samples has proven that this healing method by arc plasma is adequate for restoring the functionality of 2D nanostructures exposed to harsh environments.

关键词: graphene platelet networks     anodic arc discharge     plasma healing     scanning electron microscopy     Raman spectroscopy    

等离子表面冶金技术的现状与发展

徐重

《中国工程科学》 2002年 第4卷 第2期   页码 36-41

摘要:

双层辉光离子渗金属技术已成功地在普通碳钢表面形成高速钢、其中包括时效硬化高速钢、不锈钢以及镍基合金等;该技术已成功地应用于手用锯条和机用锯条,使其齿部形成高速钢,锯条不仅具有高速钢的切削性能,而且柔韧不断;钛合金表面经离子渗钼等工处理后,Ti6Al4V的耐磨性得到大幅度提高;经离子渗铌等工艺处理后,TiAl金属间化合物的抗高温氧化性能明显改善。

在双层辉光离子渗金属技术的基础上,又发展了加弧辉光离子渗金属,双辉钎焊技术,双阴极辉光放电超硬薄膜合成技术,以及陶瓷表面金属化和异性材料焊接技术等。

关键词: 等离子体     等离子表面冶金     双层辉光离子渗金属    

A non-lithographic plasma nanoassembly technology for polymeric nanodot and silicon nanopillar fabrication

Athanasios Smyrnakis, Angelos Zeniou, Kamil Awsiuk, Vassilios Constantoudis, Evangelos Gogolides

《化学科学与工程前沿(英文)》 2019年 第13卷 第3期   页码 475-484 doi: 10.1007/s11705-019-1809-0

摘要: In this work, we present plasma etching alone as a directed assembly method to both create the nanodot pattern on an etched polymeric (PMMA) film and transfer it to a silicon substrate for the fabrication of silicon nanopillars or cone-like nanostructuring. By using a shield to control sputtering from inside the plasma reactor, the size and shape of the resulting nanodots can be better controlled by varying plasma parameters as the bias power. The effect of the shield on inhibitor deposition on the etched surfaces was investigated by time-of-flight secondary ion mass spectroscopy (ToF-SIMS) measurements. The fabrication of quasi-ordered PMMA nanodots of a diameter of 25 nm and period of 54 nm is demonstrated. Pattern transfer to the silicon substrate using the same plasma reactor was performed in two ways: (a) a mixed fluorine-fluorocarbon-oxygen nanoscale etch plasma process was employed to fabricate silicon nanopillars with a diameter of 25 nm and an aspect ratio of 5.6, which show the same periodicity as the nanodot pattern, and (b) high etch rate cryogenic plasma process was used for pattern transfer. The result is the nanostructuring of Si by high aspect ratio nanotip or nanocone-like features that show excellent antireflective properties.

关键词: plasma     nanoassembly     etching     nanodots     nanopillars     nanofabrication    

A review on application of dielectric barrier discharge plasma technology on the abatement of volatile

Wenjing Lu, Yawar Abbas, Muhammad Farooq Mustafa, Chao Pan, Hongtao Wang

《环境科学与工程前沿(英文)》 2019年 第13卷 第2期 doi: 10.1007/s11783-019-1108-5

摘要:

• Applications of non-thermal plasma reactors for reduction of VOCs were reviewed.

• Dielectric barrier discharge (DBD) plasma was considered.

• Effect of process parameters was studied.

• Effect of catalysts and inhibitors were evaluated.

关键词: Non-thermal plasma (NTP)     Dielectric barrier discharge (DBD)     Volatile organic compounds (VOCs)     Abatement     Input power    

A review of the scalable nano-manufacturing technology for flexible devices

Wenbin HUANG,Xingtao YU,Yanhua LIU,Wen QIAO,Linsen CHEN

《机械工程前沿(英文)》 2017年 第12卷 第1期   页码 99-109 doi: 10.1007/s11465-017-0416-3

摘要:

Recent advances in electronic and photonic devices, such as artificial skin, wearable systems, organic and inorganic light-emitting diodes, have gained considerable commercial and scientific interest in the academe and in industries. However, low-cost and high-throughput nano-manufacturing is difficult to realize with the use of traditional photolithographic processes. In this review, we summarize the status and the limitations of current nano-patterning techniques for scalable and flexible functional devices in terms of working principle, resolution, and processing speed. Finally, several remaining unsolved problems in nano-manufacturing are discussed, and future research directions are highlighted.

关键词: flexible nano-manufacturing     flexible devices     nanofabrication     scalability    

纳米测量仪器和纳米加工技术

姚骏恩

《中国工程科学》 2003年 第5卷 第1期   页码 33-37

摘要:

纳米科技是当今国际上的一个热点。文章对纳米科技作了简要介绍, 纳米测量和加工是纳米科技中的一个不可缺少的重要组成部分。叙述了发展纳米测量和纳米加工技术的两个主要途径:一是发展传统技术,主要是电子显微术以及最近发展起来的聚焦离子束(FIB)- 电子束数控加工中心;二是创造新的测量仪器,建立新原理和新方法,介绍了国内外电子显微镜和扫描探针显微镜这两类纳米测量分析仪器的发展、应用和生产现状。指出我国电子显微仪器和扫描探针显微镜的开发和生产面临困境,应尽快建立和加强自己的电子显微仪器和扫描探针显微镜等纳米测量和纳米加工设备制造产业,并列入国家科技发展规划。

关键词: 纳米科技     纳米测量     电子显微镜     扫描探针显微镜     聚焦离子束-电子束装置     仪器生产    

Diagnostic evaluation of plasma aldosterone concentration to plasma renin activity ratio in primary aldosteronism

ZHANG Huilan, WANG Daowen

《医学前沿(英文)》 2008年 第2卷 第1期   页码 11-14 doi: 10.1007/s11684-008-0003-4

摘要: Using the plasma aldosterone concentration to plasma renin activity ratio (PAC/PRA ratio) as the screening test of choice for primary aldosteronism in hypertensive patients, we studied the clinical characteristics and the diagnostic value of PAC/PRA ratio in primary aldosteronism. The plasma aldosterone concentration (PAC) and plasma renin activity (PRA) levels were measured by radioimmunoassay in 902 hypertensive patients from out-patient clinics or hospitals. One hundred and twenty-six suspected primary aldosteronism patients whose PAC/PRA ratio was > 25 ng/dL/ng/mL/hr had a lamellar computed tomography (CT) scan in the adrenal gland and follow-up visits. The proportion of primary aldosteronism in hypertensive patients was 14% (126/902). There were 54 patients with unilateral or bilateral hyperplasia and 25 patients with adenoma according to the CT scan. 39% (49/126) of the patients with primary aldosteronism had hypokalemia. Twenty-five patients received surgical treatment. The efficacy and cure rates were 100% (25/25) and 48% (12/25), respectively. The effective rate of aldactone and the single-drug cure rate were 89% (48/54) and 24% (13/54), respectively. Primary aldosteronism affects over 10% of hypertensive patients in China. The PAC/PRA ratio can be considered as a routine screening test in hypertensives, especially resistant hypertensive patients and a high PAC/PRA ratio is an invaluable index in primary aldosteronism diagnosis.

Important parameters in plasma jets for the production of RONS in liquids for plasma medicine: A brief

Anna Khlyustova, Cédric Labay, Zdenko Machala, Maria-Pau Ginebra, Cristina Canal

《化学科学与工程前沿(英文)》 2019年 第13卷 第2期   页码 238-252 doi: 10.1007/s11705-019-1801-8

摘要: Reactive oxygen and nitrogen species (RONS) are among the key factors in plasma medicine. They are generated by atmospheric plasmas in biological fluids, living tissues and in a variety of liquids. This ability of plasmas to create a delicate mix of RONS in liquids has been used to design remote or indirect treatments for oncological therapy by treating biological fluids by plasmas and putting them in contact with the tumour. Documented effects include selective cancer cell toxicity, even though the exact mechanisms involved are still under investigation. However, the “right” dose for suitable therapeutical activity is crucial and still under debate. The wide variety of plasma sources hampers comparisons. This review focuses on atmospheric pressure plasma jets as the most studied plasma devices in plasma medicine and compiles the conditions employed to generate RONS in relevant liquids and the concentration ranges obtained. The concentrations of H O , NO , NO and short-lived oxygen species are compared critically to provide a useful overview for the reader.

关键词: atmospheric plasma jets     liquids     ROS     RNS     plasma-dose    

From plasma to plasmonics: toward sustainable and clean water production through membranes

《化学科学与工程前沿(英文)》 2023年 第17卷 第12期   页码 1809-1836 doi: 10.1007/s11705-023-2339-3

摘要: The increasing demand for potable water is never-ending. Freshwater resources are scarce and stress is accumulating on other alternatives. Therefore, new technologies and novel optimization methods are developed for the existing processes. Membrane-based processes are among the most efficient methods for water treatment. Yet, membranes suffer from severe operational problems, namely fouling and temperature polarization. These effects can harm the membrane’s permeability, permeate recovery, and lifetime. To mitigate such effects, membranes can be treated through two techniques: plasma treatment (a surface modification technique), and treatment through the use of plasmonic materials (surface and bulk modification). This article showcases plasma- and plasmonic-based treatments in the context of water desalination/purification. It aims to offer a comprehensive review of the current developments in membrane-based water treatment technologies along with suggested directions to enhance its overall efficiency through careful selection of material and system design. Moreover, basic guidelines and strategies are outlined on the different membrane modification techniques to evaluate its prerequisites. Besides, we discuss the challenges and future developments about these membrane modification methods.

关键词: water treatment     membrane-based process     plasma treatment     plasma polymerization     plasmonic     light-to-heat conversion    

Atomistic simulations of plasma catalytic processes

Erik C. Neyts

《化学科学与工程前沿(英文)》 2018年 第12卷 第1期   页码 145-154 doi: 10.1007/s11705-017-1674-7

摘要: There is currently a growing interest in the realisation and optimization of hybrid plasma/catalyst systems for a multitude of applications, ranging from nanotechnology to environmental chemistry. In spite of this interest, there is, however, a lack in fundamental understanding of the underlying processes in such systems. While a lot of experimental research is already being carried out to gain this understanding, only recently the first simulations have appeared in the literature. In this contribution, an overview is presented on atomic scale simulations of plasma catalytic processes as carried out in our group. In particular, this contribution focusses on plasma-assisted catalyzed carbon nanostructure growth, and plasma catalysis for greenhouse gas conversion. Attention is paid to what can routinely be done, and where challenges persist.

关键词: atomic scale simulation     plasma-catalyst    

Plasma-catalysis: Is it just a question of scale?

J. Christopher Whitehead

《化学科学与工程前沿(英文)》 2019年 第13卷 第2期   页码 264-273 doi: 10.1007/s11705-019-1794-3

摘要: The issues of describing and understanding the changes in performance that result when a catalyst is placed into plasma are discussed. The different chemical and physical interactions that result and how their combination might produce beneficial results for the plasma-catalytic processing of different gas streams are outlined with particular emphasis being placed on the different range of spatial and temporal scales that must be considered both in experiment and modelling. The focus is on non-thermal plasma where the lack of thermal equilibrium creates a range of temperature scales that must be considered. This contributes in part to a wide range of inhomogeneity in different properties such as species concentrations and electric fields that must be determined experimentally by methods and be incorporated into modelling. It is concluded that plasma-catalysis is best regarded as conventional catalysis perturbed by the presence of a discharge, which modifies its operating conditions, properties and outcomes often in a very localised way. The sometimes used description “plasma-activated catalysis” is an apt one.

关键词: plasma catalysis     plasma-activated catalysis     non-thermal plasma     CO2 conversion    

Submerged arc plasma system combined with ozone oxidation for the treatment of wastewater containing

《环境科学与工程前沿(英文)》 2021年 第15卷 第5期 doi: 10.1007/s11783-020-1384-0

摘要:

• Submerged arc plasma was introduced in terms of wastewater treatment.

关键词: Thermal plasma     Submerged arc plasma     Wastewater     Ozone     Phenol     Highly energetic electron    

Water-dispersible nano-pollutions reshape microbial metabolism in type-specific manners: A metabolic

《环境科学与工程前沿(英文)》 2022年 第16卷 第9期 doi: 10.1007/s11783-022-1548-1

摘要:

• Water-dispersible nano-pollutions exhibit type-specific toxic effects on E. coli.

关键词: Nano-toxicity     Nano-plastics     Quantum dots     Microbial metabolite     Metabolic dysregulation    

Modelling and diagnostics of multiple cathodes plasma torch system for plasma spraying

Kirsten BOBZIN, Nazlim BAGCIVAN, Lidong ZHAO, Ivica PETKOVIC, Jochen SCHEIN, Karsten HARTZ-BEHREND, Stefan KIRNER, José-Luis MARQUéS, Günter FORSTER

《机械工程前沿(英文)》 2011年 第6卷 第3期   页码 324-331 doi: 10.1007/s11465-011-0125-2

摘要:

Usage of a multiple-arcs system has significantly improved process stability and coating properties in air plasma spraying. However, there are still demands on understanding and controlling the physical process to determine process conditions for reproducible coating quality and homogeneity of coating microstructure. The main goal of this work is the application of numerical simulation for the prediction of the temperature profiles at the torch outlet for real process conditions. Behaviour of the gas flow and electric arcs were described in a three-dimensional numerical model. The calculated results showed the characteristic triangular temperature distribution at the torch nozzle outlet caused by three electric arcs. These results were compared with experimentally determined temperature distributions, which were obtained with specially developed computed tomography equipment for reconstructing the emissivity and temperature distribution of the plasma jet close to the torch exit. The calculated results related to temperature values and contours were verified for the most process parameters with experimental ones.

关键词: plasma spraying     electric arc     three-cathode plasma torch     numerical simulation     computed tomography    

标题 作者 时间 类型 操作

Kinetic Monte Carlo simulations of plasma-surface reactions on heterogeneous surfaces

Daniil Marinov

期刊论文

Plasma-enabled healing of graphene nano-platelets layer

Xiuqi Fang, Carles Corbella, Denis B. Zolotukhin, Michael Keidar

期刊论文

等离子表面冶金技术的现状与发展

徐重

期刊论文

A non-lithographic plasma nanoassembly technology for polymeric nanodot and silicon nanopillar fabrication

Athanasios Smyrnakis, Angelos Zeniou, Kamil Awsiuk, Vassilios Constantoudis, Evangelos Gogolides

期刊论文

A review on application of dielectric barrier discharge plasma technology on the abatement of volatile

Wenjing Lu, Yawar Abbas, Muhammad Farooq Mustafa, Chao Pan, Hongtao Wang

期刊论文

A review of the scalable nano-manufacturing technology for flexible devices

Wenbin HUANG,Xingtao YU,Yanhua LIU,Wen QIAO,Linsen CHEN

期刊论文

纳米测量仪器和纳米加工技术

姚骏恩

期刊论文

Diagnostic evaluation of plasma aldosterone concentration to plasma renin activity ratio in primary aldosteronism

ZHANG Huilan, WANG Daowen

期刊论文

Important parameters in plasma jets for the production of RONS in liquids for plasma medicine: A brief

Anna Khlyustova, Cédric Labay, Zdenko Machala, Maria-Pau Ginebra, Cristina Canal

期刊论文

From plasma to plasmonics: toward sustainable and clean water production through membranes

期刊论文

Atomistic simulations of plasma catalytic processes

Erik C. Neyts

期刊论文

Plasma-catalysis: Is it just a question of scale?

J. Christopher Whitehead

期刊论文

Submerged arc plasma system combined with ozone oxidation for the treatment of wastewater containing

期刊论文

Water-dispersible nano-pollutions reshape microbial metabolism in type-specific manners: A metabolic

期刊论文

Modelling and diagnostics of multiple cathodes plasma torch system for plasma spraying

Kirsten BOBZIN, Nazlim BAGCIVAN, Lidong ZHAO, Ivica PETKOVIC, Jochen SCHEIN, Karsten HARTZ-BEHREND, Stefan KIRNER, José-Luis MARQUéS, Günter FORSTER

期刊论文